Wow, some of these responses are funny.
It's quite simple as what you are doing here is very straight forward.
Decide on how much RPM you want to turn and choose the supporting components from there. If you plan on leaving it a small inch engine and not turning it past 6500 RPM or so, I would go with the 185's. If you plan on running it up to 6700-7500 I would go with the 205's. However, if you plan on running some RPM now, meaning, 7000 or so, and then later upping the cubes, I would put a 225 on it.
Oh, and by the way, get a REAL custom cam. Stay away from Comp, unless you want a shelf cam and they do have some that will make very good power, but their phone techs suck for doing custom cams. There are plenty of custom cam guys out there that can help you. There are some that are better to deal with than others.
The only reasons a large cc runner head would not work on a small inch engine, is either due to poor selection of supporting components or poor camshaft design.
A prime example is a buddy of mine has a 306 that has 240cc high ports on it and the little shit runs 9.60's all day long at 3000 lbs N/A. The key here is the RPM limit was decide upon prior to selecting anything else. So now he has a HUGE headed 306 that goes thru the traps at 9000+ RPM!! The point is the engine is going to move a certain volume of air based on cubic inch and rpm. If you select parts to support that volume it will make good power.